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Stochastic and dynamic views of chemical reaction kinetics in solutions

Stochastic and dynamic views of chemical reaction kinetics in solutions - PPUR - 9782880743796 -
Stochastic and dynamic views of chemical reaction kinetics in solutions 

Auteur : 

Editeur : PPUR

Collection : cahiers de chimie

Date parution :

The book is devoted to the stochastic approach to the theoretical description of chemical reaction kinetics in condensed phase, based on Langevin or Fokker-Planck equations for the motion along the reaction co-ordinate. This method is often opposed to the 'dynamic' one, used in the works on quantum mechanical theory of non-adiabatic reactions, although in fact they are not antagonists. The goal of the book is to describe both approaches and to demonstrate the relationship between them. The book involves an introduction into stochastic methods for charge transfer reactions and presents a detailed comparison of new approach with more traditional ones. The presentation of the major material is rather simple and detailed, and uses various analogies and cross-references to different parts of the book. This makes the book easy for the students. It will be also useful for the postgraduates and researchers working in chemical kinetics, since it involves many results and final equations, and may be used in the teaching courses and scientific studies.

Auteurs :

Alexander M. Kuznetsov (born January 5, 1938 in Moscow) is graduate from the institute of Physical Engineers with the speciality 'Theoretical nuclear physics' and entered the Institute of Electrochemistry of Russian Academy of Sciences. At present, he is the head of the Theoretical Department of this Institute, Professor of theoretical physics.


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Descriptif : 

Reliure :
Broché
Nbr de pages :
261
Dimension :
15 x 21 x 1.6 cm
Poids :
365 gr
ISBN 10 :
2880743796
ISBN 13 :
9782880743796
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Sommaire

GENERAL DESCRIPTION OF STOCHASTIC PROCESSES
Stochastic processes in life and nature
Distribution functions
Markovian process
CHEMICAL REACTIONS IN CONDENSED PHASE: A STOCHASTIC VIEW
Stochastic approach to chemical reaction kinetics
Classical transitions over one-dimensional potential barrier
Stochastic views of electron transfer reactions
Adiabatic and non-adiabatic electron transitions in stochastic approach
Classical stochastic motion in multidimensional reactive mode set
Classical transitions in the two-mode system
Application of multidimensional stochastic description to the electron transfer
Proton transfer
Atom and atomic group transfer in polar solvent
DYNAMIC MODELS OF STOCHASTIC BEHAVIOUR
Stochastic behavior evolving from dynamic models
Effective hamiltonian method in electron transfer processes
Ionic dynamics in polar solvent
Rates of non-adiabatic reactions
Equivalence of stochastic and dynamic description
Dynamic and stochastic effects in bridge-assisted electron transfer